The methods work because radioactive elements are unstable, and they are always trying to move to a more stable state. This process by which an unstable atomic nucleus loses energy by releasing radiation is called radioactive decay.
The thing that makes this decay process so valuable for determining the age of an object is that each radioactive isotope decays at its own fixed rate, which is expressed in terms of its half-life.
We can see how do deal with this if we take a particular case. For example the amount of Rb in mantle rocks is generally low, i.e. The mantle thus has a low If these two independent dates are the same, we say they are concordant.Prior to 1905 the best and most accepted age of the Earth was that proposed by Lord Kelvin based on the amount of time necessary for the Earth to cool to its present temperature from a completely liquid state.Although we now recognize lots of problems with that calculation, the age of 25 my was accepted by most physicists, but considered too short by most geologists. Recognition that radioactive decay of atoms occurs in the Earth was important in two respects: Principles of Radiometric Dating Radioactive decay is described in terms of the probability that a constituent particle of the nucleus of an atom will escape through the potential (Energy) barrier which bonds them to the nucleus.Radiometric dating, or radioactive dating as it is sometimes called, is a method used to date rocks and other objects based on the known decay rate of radioactive isotopes.Different methods of radiometric dating can be used to estimate the age of a variety of natural and even man-made materials.